Mössbauer studies of coordination compounds using synchrotron radiation
نویسندگان
چکیده
منابع مشابه
Synchrotron Mössbauer spectroscopy using high-speed shutters
A new method of performing Mössbauer spectroscopy with synchrotron radiation is demonstrated that involves using a high-speed periodic shutter near the focal spot of a microfocused X-ray beam. This fast microshuttering technique operates without a high-resolution monochromator and has the potential to produce much higher signal rates. It also offers orders of magnitude more suppression of unwan...
متن کاملSynchrotron-based Nickel Mössbauer Spectroscopy.
We used a novel experimental setup to conduct the first synchrotron-based (61)Ni Mössbauer spectroscopy measurements in the energy domain on Ni coordination complexes and metalloproteins. A representative set of samples was chosen to demonstrate the potential of this approach. (61)NiCr2O4 was examined as a case with strong Zeeman splittings. Simulations of the spectra yielded an internal magnet...
متن کاملContemporary X-ray electron-density studies using synchrotron radiation
Synchrotron radiation has many compelling advantages over conventional radiation sources in the measurement of accurate Bragg diffraction data. The variable photon energy and much higher flux may help to minimize critical systematic effects such as absorption, extinction and anomalous scattering. Based on a survey of selected published results from the last decade, the benefits of using synchro...
متن کاملErratum: 61Ni synchrotron radiation-based Mössbauer spectroscopy of nickel-based nanoparticles with hexagonal structure
We measured the synchrotron-radiation (SR)-based Mössbauer spectra of Ni-based nanoparticles with a hexagonal structure that were synthesised by chemical reduction. To obtain Mössbauer spectra of the nanoparticles without (61)Ni enrichment, we developed a measurement system for (61)Ni SR-based Mössbauer absorption spectroscopy without X-ray windows between the (61)Ni84V16 standard energy alloy ...
متن کاملMaterials Analysis Using Synchrotron Radiation
Synchrotron radiation (SR) is a tunable, highly oriented, intense X-ray. Its tunability has led to XAFS being used as a common analytical tool, and is particularly useful for examining local structures. In fact, its use is indispensable to the examination of not only amorphous materials or solutions but also multicomponent systems. Thanks to the high intensity of SR, it is possible to determine...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Coordination Chemistry Reviews
سال: 2005
ISSN: 0010-8545
DOI: 10.1016/j.ccr.2004.03.005